Use of Ultraviolet Nano
light emitting diodes In Forensic Science
INTRODUCTION:
LED are semiconductor p-n junctions that under forward bias conditions can emit radiation by electroluminescence in the UV, visible or infrared regions of the electromagnetic spectrum. The quanta of light energy released is approximately proportional to the band gap of the semiconductor.Explanation:
A light-emitting diode (LED) is a two-lead semiconductor light source. It is a basic p-n junction diode, which emits light when activated. OR we can say that A light emitting diode (LED) is essentially a PN junction opto-semiconductor that emits a monochromatic (single color) light when operated in a forward biased direction.
LEDs convert electrical energy into light energy.When a fitting voltage is applied to the leads, electrons are able to recombine with electron holes within the device, releasing energy in the form of photons. This effect is called electroluminescence, and the color of the light (corresponding to the energy of the photon) is determined by the energy band gap of the semiconductor.
Nitride-based semiconductors, such as GaN, InGaN and AlGaN, are materials that are used in ubiquitous white, blue and green LEDs, and laser diodes (for Blu-ray players) which is a huge industry with a multi-billion dollar market. The technologies of these semiconductors have progressed and matured enormously over the last two decades and has resulted in very low cost production for these devices.
Ultraviolet (UV) light is electromagnetic radiation with a wavelength shorter than that of visible light but longer than X-rays. Though usually invisible, under some conditions children and young adults can see ultraviolet down to wavelengths of about 310 nm,[1][2] and people with aphasia (missing lens) can also see some UV wavelengths. Near-UV is visible to a number of insects and birds.
The Nano LED range is a novel and economical light source system that utilizes laser diode and LED technology to generate short optical pulses over a wide range of repetition rates and wavelengths. Optical pulses as short as 70ps can be generated at repetition rates up to 1MHz.
The Nano LED package consists of a Nano LED controller and a range of interchangeable Nano LED sources, each designed to be used over a specific wavelength range. LED based sources generate nanosecond pulses, while laser diode based sources generate picosecond pulses.
Each Nano LED source contains adjustable collection optics and a bayonet mounting flange to make incorporation into any optical system easy. Dedicated drive electronics in each Nano LED source means that plug-n-play operation is possible across the Nano LED range. A synchronization output allows straightforward triggering of your existing data acquisition electronics.
The GaN-AlN material system is well suited for UV optoelectronic devices (emitters, detectors and optical modulators) because its energy gap can be tuned by changing its alloy composition to cover all three regions of the UV electromagnetic spectrum {UV-A (340-400 nm), UV-B (290-340 nm) and UV-C (200-290 nm).
Applications of UV Light:
There are many applications that utilize the UV region of the electromagnetic spectrum such as water sterilization, air purification, surface disinfection, free-space non-line-of-sight covert communication, epoxy curing, counterfeit detection, light therapy and fluorescence identification of biological/chemical agents. AlGaN is a good candidate as it has a large band gap that corresponds to the UV range and also the maturity of LED technology.
Light-emitting diodes (LEDs) can be manufactured to emit light in the ultraviolet range, although practical LED arrays are very limited below 365 nm. LED efficiency at 365 nm is about 5–8%, whereas efficiency at 395 nm is closer to 20%, and power outputs at these longer UV wavelengths are also better. Such LED arrays are beginning to be used for UV curing applications, and are already successful in digital print applications and inert UV curing environments. Power densities approaching 3 W/cm2 (30 kW/m2) are now possible, and this, coupled with recent developments by photo initiator and resin formulators, makes the expansion of LED-cured UV materials likely.
Literature Review:
In 1907 British scientist H. J. Round of Marconi Labs discovered that some inorganic Substances glow if an electric voltage is impress on them. Henry J. Round discovered the physical effect of electroluminescence, an optical and electrical phenomenon in which a material emits light in response to an electric current passed through it or to a strong electric field. In 1927 The Russian Oleg Vladimirovich Losev independently reported on the creation of an LED, but no practical use was made of the discovery. In 1961 Bob Biardand and Gary Pittman (Texas Instruments) find out that gallium arsenide (GaAs) give off infrared radiation when electric current is applied. They receive a patent for this diode the light produced was very dim and not bright enough to stimulate further research.
I. Father Of LED:
In 1962 the first visible spectrum LED light was produced by Nick Holon yak Jr., a consulting engineer for General Electric Company and it was red in color. This coined his nickname, 'Father of the Light Emitting Diode'.
He also holds 41 patents and his other inventions include the laser diode and the first light dimmer. (Another interesting fact about Holon yack was that he was once the student of John Bardeen, the co-inventor of the transistor.)
The red LED's were not bright enough to be seen in daylight so the first LED applications were mainly used as indicator lights for military use. In 1972, electrical engineer, M George Crawford a student of Holon yak, invented the first yellow colored LED for the Monsanto Company using gallium arsenide phosphide in the diode. Crawford also invented a red LED that was 10 times brighter than Holon yak’s.
II. First Visible LEDs:
It should be noted that the Monsanto Company was the first to produce visible LEDs. In 1968, Monsanto produced red LEDs used as indicators. But it was not until the 1970s that LEDs became popular, as technology progressed in the 1970's additional colors were created and as new colors became available, new uses for LED lights were in demand. LED's were used in applications such as calculators, digital watches and test devices.
When Fairchild Optoelectronics began producing low-cost LED devices (less than five cents each) for manufacturers. LEDs became popular.
III. LEDs in telecommunication:
In 1976, Thomas P. Pearsall invented a high-efficiency and extremely bright LED for use in fiber optics and fiber telecommunications. Pearsall invented new semiconductor materials optimized for optical fiber transmission wavelengths. The first super bright LED's were developed in the 1980's and were brighter, more stable and cost efficient which saw the demand for LED's rise dramatically.
From 1990 the use of LED's became standard in various industrial applications from switch cabinets to measuring instruments, in consumer products such as Hi-Fi equipment, telephones or personal computers and in traffic signal installations for road and railway or in indoor and outdoor automotive lighting.
Gallium Nitride LEDs:
In 1994, Shuji Nakamura invented the first blue LED using gallium nitride. For two decades LED lights have been replacing incandescent globes in homes and businesses, offering a cheaper, more efficient service in a wide variety of contexts. Ultraviolet light-emitting diodes (UV-LEDs) have started replacing UV lamps. The power per LED of high-power LED products has reached 12 W (14 A), which is 100 times the values Observed ten years ago. In addition, the cost of these high-power LEDs has been decreasing.
Zheludev, N. (2007). "The life and times of the LED: a 100-year history"
IV. UV nano LEDs
Here we started the development of the world's first ultraviolet light-emitting diodes (UV-LEDs) in collaboration with the University of Tokushima in April 2000, and have been supplying related products ever since. In recent years, as people are becoming more concerned about protecting the environment the role of UV-LEDs is becoming more important.
UV-LEDs are LEDs that emit UV rays with a wavelength of approximately 400nm or shorter. They are divided into near-ultraviolet light-emitting diodes (NUV-LEDs), whose emission wavelength is approximately 300 to 400nm, and deep-ultraviolet LEDs (DUV-LEDs), whose emission wavelength is approximately 200 to 300nm. UV-LEDs are promising candidates for various applications: replacing UV lamps; fluorescence light sources for
lighting and displays; high-resolution light sources for microscopes and exposure machines; light sources for chemical excitation as used for resin curing, medicine, and biotechnology; excitation light sources for spectroscopy as used for banknote identification, DNA chips, and environmental monitoring; sanitary light sources for disinfection and sterilization (figure?1)
UV-LEDs that emit light at a power of a few mill watts have already replaced UV lamps for banknote identification in automated teller machines. Prototype light sources for resin curing and exposure machines (which require a large cumulative light intensity) have been made, and commercial products are being released accordingly. The external quantum efficiency of NUV-LED, in particular, has greatly improved because of developments in crystal growth, chip processing, and packaging technologies, reaching 30% at a wavelength of 365nm, 50% at 385nm, and 60% at 405nm. The power per LED of high-power products at a wavelength of 365nm has reached 12W, which is 100times the values from ten years ago, 118 mW. The cost of these high-power LEDs has decreased as a result of mass production, making them available for various applications.
The researchers, Yu-Jung Lu, et al., from National Tsing-Hua University in Hsinchu, Taiwan, have published their study on the nano-LEDs in a recent issue of Applied Physics Letters.
UV LED Exposure Box
The new nano-LEDs have a unique structure that consists of 40-nm-thick nano disks sandwiched between two layers of nano rods, resulting in a nano disk-in-nano rod geometry. The nano disks are made of indium gallium nitride (InGaN), a semiconducting material that is widely used in LEDs and solar cells, while the nano rods are made of gallium nitride (GaN). However, InGaN LEDs capable of emitting light of the entire visible spectrum have not been achieved until now.
Poensgen, Tobias (January 22, 2013) InfiniLED MicroLEDs achieve Ultra-High Light Intensity
The InGaN/GaN nano disk/nano rod structure is similar to a well-known quantum well structure, but in a reduced dimensionality (reduction in lateral sizes),” coauthor Shangjr Gwo, a physics professor at National Tsing-Hua University, told PhysOrg.com. “The InGaN nano disks sandwiched between the p- and n-GaN regions act as the full-color visible-light emitters when electrons and holes are injected across the p-n junction at a forward bias voltage. The electroluminescent light comes from the electron-hole recombination within the InGaN nanodisks.”
As the researchers explained, the key to achieving full-color LEDs was overcoming large lattice strains, which degrade long-wavelength emissions. The InGaN/GaN nano rod system resolves this issue due to the strain relaxation in the nanostructured geometry.
The researchers hope that these full-color nano-LEDs can be used in high-resolution imaging techniques that can resolve ultra-small sub wavelength features of objects. To do this, these techniques must overcome the diffraction limit, which is a fundamental limit on imaging resolution caused by the spreading out of waves.
http://phys.org/news/2011-06-nano-leds-emit-full-visible-spectrum.html#jCp
Expected Results:
As at a crime scene, fast and accurate detection of possible traces is of vital importance. Many biological fluids are fluorescent in nature, when such traces are illuminated with light of the right wavelength, they fluoresce and are detectable to the investigator. Crime scene determines choice of filter the degree to which various substances become visible when using different filters depends on the state of the substance (trace) and the surface on which the substance exists. Therefore it can be predicted that UV LEDs will e more efficient for these purposes in future for many forensic purposes such as collecting only blood stains excluding other unnecessary stains on clothes or different body parts in case of any murder or any other crime investigation. The conditions of the crime scene often will determine which sort of light (i.e.. wavelength) will be most effective. These UV LEDs if used for these purposes instead of old fluorescent lights then it will have many advantages which he old has not including lower power consumption, long life time, high versatility regarding the size of illuminated area.So this will be a great invention in that kind of crime investigation.
References:
1. Theodore D. Moustakas, Yitao Liao, Chen-kai Kao, Christos Thomidis, Anirban Bhattacharyya, Dipesh Bhattarai and Adam Moldawer. Deep UV-LEDs with high IQE based on AlGaN alloys with strong band structure potential fluctuations
2. http://phys.org/news/2011-06-nano-leds-emit-full-visible-spectrum.html#jCp
3. S. Nikishin,B.Borisov,G.Kipshidze,V.Kuryatkov,M.Holtz, and H.Temkin,.UV LEDs
4. Yoshihiko Muramoto, Masahiro Kimura and Suguru Nouda future of ultraviolet light-emitting diodes: UV-LED will replace the UV lamp(2014)
5. Zheludev, N. (2007). "The life and times of the LED: a 100-year history"
6. Poensgen, Tobias (January 22, 2013) InfiniLED MicroLEDs achieve Ultra-High Light Intensity